On the frontier between nucleophilic aromatic substitution and catalysis
| Authors: | Drapeau, Martin Pichette; Ollevier, Thierry; Taillefer, Marc |
| Abstract: | A study on the arylation of heteroatom nucleophiles by using activated haloarenes, with or without metal catalysts, is reported. A discussion concerning the involvement of traces of metals is presented, supported by an unexpected ''ligand'' effect in the absence of added metal catalysts. We believe that the frontier between nucleophilic aromatic substitution and catalysis will likely prove to be much harder to delimit than is generally thought |
| Document Type: | Article de recherche |
| Issue Date: | 15 April 2014 |
| Open Access Date: | 16 March 2016 |
| Document version: | AM |
| Permalink: | http://hdl.handle.net/20.500.11794/371 |
| This document was published in: | Chemistry a European journal, Vol. 20 (2), 5231 – 5236 https://doi.org/10.1002/chem.201304164 Wiley |
| Alternative version: | 10.1002/chem.201304164 24737493 |
| Collection: | Articles publiés dans des revues avec comité de lecture |
Files in this item:
| Description | Size | Format | ||
|---|---|---|---|---|
| 2014CEJ5231.pdf | Version of Record | 255.3 kB | Adobe PDF | Request a copy |
| chem_201304164_sm_miscellaneous_information.pdf | Données supplémentaires | 10.26 MB | Adobe PDF | Request a copy |
| 2014CEJversionsoumise.pdf | 553.45 kB | Adobe PDF | View/Open |
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