Recyclable iron(II) caffeine-derived ionic salt catalyst in the Diels–Alder reaction of cyclopentadiene and α,β-unsaturated N-acyloxazolidinones in dimethyl carbonate

DC FieldValueLanguage
dc.contributor.authorMeng, Di-
dc.contributor.authorLi, Dazhi-
dc.contributor.authorOllevier, Thierry-
dc.date.accessioned2019-08-16T13:54:20Z-
dc.date.available2019-08-16T13:54:20Z-
dc.date.issued2019-07-15-
dc.identifier.issn2046-2069fr
dc.identifier.urihttp://hdl.handle.net/20.500.11794/36034-
dc.description.abstractIron(II) triflate was used in combination with caffeine-derived salts as recyclable catalysts for the Diels–Alder reaction run in dimethyl carbonate (DMC) as a green solvent. The catalyst was prepared as an ionic salt from a xanthinium salt and Fe(OTf)2. Various substrates including α,β-unsaturated carbonyl and N-acyloxazolidinone derivatives were reacted with cyclopentadiene using this recyclable catalyst. The use of a low catalyst loading (1 mol%) afforded high yields (up to 99%) of the corresponding cycloadducts. The recycling and the efficiency of the catalyst were demonstrated for several runs.fr
dc.languageengfr
dc.publisherRoyal Society of Chemistryfr
dc.titleRecyclable iron(II) caffeine-derived ionic salt catalyst in the Diels–Alder reaction of cyclopentadiene and α,β-unsaturated N-acyloxazolidinones in dimethyl carbonatefr
dc.title.alternativeRecyclable iron(II) caffeine-derived ionic salt catalyst in the Diels–Alder reaction of cyclopentadiene and alpha,beta-unsaturated N-acyloxazolidinones in dimethyl carbonatefr
dc.typeCOAR1_1::Texte::Périodique::Revue::Contribution à un journal::Article::Article de recherchefr
dcterms.bibliographicCitationRSC Advances, Vol. 38 (9), 21956–21963 (2019)fr
dc.identifier.doi10.1039/c9ra04098ffr
dc.subject.rvmChimie vertefr
dc.subject.rvmSolvantsfr
dc.subject.rvmRéaction de Diels-Alderfr
dc.subject.rvmCatalysefr
dc.subject.rvmFerfr
rioxxterms.versionVersion of Recordfr
rioxxterms.version_of_recordhttps://doi.org/10.1039/c9ra04098ffr
rioxxterms.project.funder_nameNatural Sciences and Engineering Research Council of Canadafr
rioxxterms.project.funder_nameFonds de Recherche du Québec - Nature et Technologiesfr
rioxxterms.project.funder_nameCentre in Green Chemistry and Catalysis (CGCC)fr
rioxxterms.project.funder_nameUniversité Lavalfr
rioxxterms.project.funder_nameChina Scholarship Councilfr
bul.rights.periodeEmbargo0 moisfr
bul.rights.addendumLa publication est en libre accessfr
Collection:Articles publiés dans des revues avec comité de lecture

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