[(IMes)2Pt(H)(ClBC5H4SiMe3)] : a Borabenzene–Platinum Adduct with an Unusual Pt‐Cl‐B Interaction

Authors: Languérand, AndréBarnes, Stéphanie S.Bélanger-Chabot, Guillaume; Maron, Laurent; Berrouard, Philippe; Audet, Pierre
Abstract: A Pt‐Cl‐B interaction is observed when a borabenzene derivative reacts with a platinum(0) precursor with bulky N‐heterocyclic carbene ligands. The resulting platinum(II) complex (see picture; Pt red, N blue, Cl green, B pink, Si yellow) involves a new bonding mode for borabenzene, which usually binds in an η6 fashion to transition metals.
Document Type: Article de recherche
Issue Date: 5 August 2009
Open Access Date: 9 May 2018
Document version: AM
Permalink: http://hdl.handle.net/20.500.11794/29642
This document was published in: Angewandte Chemie (International ed. in English), Vol. 48 (36), 6695-6698 (2009)
Verlag Chemie
Alternative version: 10.1002/anie.200902870
Collection:Articles publiés dans des revues avec comité de lecture

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