[(IMes)2Pt(H)(ClBC5H4SiMe3)] : a Borabenzene–Platinum Adduct with an Unusual Pt‐Cl‐B Interaction
| Authors: | Languérand, André; Barnes, Stéphanie S.; Bélanger-Chabot, Guillaume; Maron, Laurent; Berrouard, Philippe; Audet, Pierre |
| Abstract: | A Pt‐Cl‐B interaction is observed when a borabenzene derivative reacts with a platinum(0) precursor with bulky N‐heterocyclic carbene ligands. The resulting platinum(II) complex (see picture; Pt red, N blue, Cl green, B pink, Si yellow) involves a new bonding mode for borabenzene, which usually binds in an η6 fashion to transition metals. |
| Document Type: | Article de recherche |
| Issue Date: | 5 August 2009 |
| Open Access Date: | 9 May 2018 |
| Document version: | AM |
| Permalink: | http://hdl.handle.net/20.500.11794/29642 |
| This document was published in: | Angewandte Chemie (International ed. in English), Vol. 48 (36), 6695-6698 (2009) https://doi.org/10.1002/anie.200902870 Verlag Chemie |
| Alternative version: | 10.1002/anie.200902870 19658146 |
| Collection: | Articles publiés dans des revues avec comité de lecture |
Files in this item:
| Description | Size | Format | ||
|---|---|---|---|---|
| FV_borabenzene-REVISIONFINALE.pdf | 2.42 MB | Adobe PDF |  View/Open |
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