Iron-catalyzed carbene insertion reactions of alpha-diazoesters into Si-H bonds

Authors: Keipour, HodaOllevier, Thierry
Other Title(s): Iron-catalyzed carbene insertion reactions of α-diazoesters into Si-H bonds
Abstract: An efficient iron-catalyzed carbene insertion reaction of α-diazo carbonyl compounds into the Si–H bond was developed. A wide range of α-silylesters was obtained in high yields (up to 99%) from α-diazoesters using a simple iron(II) salt as catalyst.
Document Type: Article de recherche
Issue Date: 13 October 2017
Open Access Date: 13 October 2018
Document version: AM
This document was published in: Organic letters, Vol. 19 (21), 5736–5739 (2017)
American Chemical Society
Alternative version: 10.1021/acs.orglett.7b02488
Collection:Articles publiés dans des revues avec comité de lecture

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