Iron(II)-catalyzed enantioselective meso-epoxide-opening with anilines
| Authors: | Plancq, Baptiste; Ollevier, Thierry |
| Abstract: | A highly enantioselective method for the catalytic opening of aromatic meso-epoxides with aniline derivatives was developed. The desired chiral ß-amino alcohols were obtained in mostly good to very good yields with excellent enantioselectivities. Structural evidence of the pre-catalyst revealed a scarcely disclosed heptadentate Fe(II) complex with the chiral bipyridine ligand |
| Document Type: | Article de recherche |
| Issue Date: | 27 January 2012 |
| Open Access Date: | 8 February 2017 |
| Document version: | AM |
| Permalink: | http://hdl.handle.net/20.500.11794/13434 |
| This document was published in: | Chemical communications (Cambridge, England), Vol. 48 (32), 3806-3808 (2012) https://doi.org/10.1039/c2cc18032d Royal Society of Chemistry |
| Alternative version: | 10.1039/c2cc18032d 22315046 |
| Collection: | Articles publiés dans des revues avec comité de lecture |
Files in this item:
| Description | Size | Format | ||
|---|---|---|---|---|
| 2012CCsubmittedversion.pdf | 606.29 kB | Adobe PDF |  View/Open |
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