Iron(II)-catalyzed enantioselective meso-epoxide-opening with anilines

Authors: Plancq, BaptisteOllevier, Thierry
Abstract: A highly enantioselective method for the catalytic opening of aromatic meso-epoxides with aniline derivatives was developed. The desired chiral ß-amino alcohols were obtained in mostly good to very good yields with excellent enantioselectivities. Structural evidence of the pre-catalyst revealed a scarcely disclosed heptadentate Fe(II) complex with the chiral bipyridine ligand
Document Type: Article de recherche
Issue Date: 27 January 2012
Open Access Date: 8 February 2017
Document version: AM
This document was published in: Chemical communications (Cambridge, England), Vol. 48 (32), 3806-3808 (2012)
Royal Society of Chemistry
Alternative version: 10.1039/c2cc18032d
Collection:Articles publiés dans des revues avec comité de lecture

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