Atom economical synthesis of N-alkylbenzamides via iron(III) sulfate catalyzed rearrangement of 2-alkyl-3-aryloxaziridines in water and in the presence of surfactant

Authors: Kraïem, JamilOllevier, Thierry
Abstract: A green and mild synthetic route to N-alkylbenzamides involves eco-friendly one pot synthesis of 2-alkyl-3-aryloxaziridines from N-alkylamines and benzaldehydes followed by iron(III) sulfate catalyzed rearrangement to the corresponding amides in water as solvent and in the presence of sodium dodecyl sulfate as surfactant. This green approach affords N-alkylbenzamides in high overall yields under simple and minimum manipulation.
Document Type: Article de recherche
Issue Date: 23 January 2017
Open Access Date: 23 January 2018
Document version: AM
This document was published in: Green Chemistry (2017)
Royal Society of Chemistry
Alternative version: 10.1039/C6GC03589B
Collection:Articles publiés dans des revues avec comité de lecture

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