On the frontier between nucleophilic aromatic substitution and catalysis

Authors: Drapeau, Martin Pichette; Ollevier, Thierry; Taillefer, Marc
Abstract: A study on the arylation of heteroatom nucleophiles by using activated haloarenes, with or without metal catalysts, is reported. A discussion concerning the involvement of traces of metals is presented, supported by an unexpected ''ligand'' effect in the absence of added metal catalysts. We believe that the frontier between nucleophilic aromatic substitution and catalysis will likely prove to be much harder to delimit than is generally thought
Document Type: Article de recherche
Issue Date: 15 April 2014
Open Access Date: 16 March 2016
Document version: AM
Permalink: http://hdl.handle.net/20.500.11794/371
This document was published in: Chemistry a European journal, Vol. 20 (2), 5231 – 5236
http://dx.doi.org/10.1002/chem.201304164
Wiley
Alternative version: 10.1002/chem.201304164
24737493
Collection:Articles publiés dans des revues avec comité de lecture

Files in this item:
Description SizeFormat 
2014CEJ5231.pdf
Version of Record255.3 kBAdobe PDF    Request a copy
chem_201304164_sm_miscellaneous_information.pdf
Données supplémentaires10.26 MBAdobe PDF    Request a copy
2014CEJversionsoumise.pdf553.45 kBAdobe PDFView/Open
All documents in CorpusUL are protected by Copyright Act of Canada.